| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 69031 | Journal of Molecular Catalysis A: Chemical | 2006 | 5 Pages |
New non-C2-symmetric chiral diphosphites have been synthesized and used as ligands in the rhodium catalyzed enantioselective and regioselective hydroformylation of styrene. A synergistic effect improving both activity and enantioselectivity is observed when a chiral dithiourea is introduced as co-ligand in the Rh-diphosphite catalytic system.
Graphical abstractNew non-C2-symmetric chiral diphosphites have been synthesized and used as ligands in the rhodium catalyzed enantioselective and regioselective hydroformylation of styrene. A synergistic effect improving both activity and enantioselectivity is observed when a chiral dithiourea is introduced as co-ligand in the Rh-diphosphite catalytic system .Figure optionsDownload full-size imageDownload as PowerPoint slide
