Article ID Journal Published Year Pages File Type
69074 Journal of Molecular Catalysis A: Chemical 2006 6 Pages PDF
Abstract

A reagent combination of SnCl2 and catalytic [Ir(COD)Cl]2 (1 mol%) in THF–H2O promotes the reaction of allyl alcohol and aldehyde leading to homoallyl alcohols in good to excellent yields. Control studies suggest the plausible participation of π-allyl-iridium intermediate(s) from which direct allyl transfer takes place to aldehyde.

Graphical abstractFacile one-carbon homologation of allyl alcohol to homoallyl alcohol using IrI–SnCl2 as reagent is described, which might involve the intermediacy of a π-allyl-iridium intermediate. Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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