Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
69123 | Journal of Molecular Catalysis A: Chemical | 2006 | 5 Pages |
Monoallyl guaiacol such as eugenol, o-eugenol and chavibetol are industrially important compounds, which were synthesized by the allylation of guaiacol using zeolite HY. The reaction was performed in an autoclave in the temperature range 140–200 °C and allyl alcohol to guaiacol mole ratio 1:4, under nitrogen pressure. Among zeolites, HY gave maximum guaiacol conversion (46%) compared to H-beta (28%), H-mordenite (15%) and HZSM-5 (4%) when compared under identical reaction conditions. Zeolites showed better selectivity (>85%) for monoallyl guaiacol than K-10 montmorillonite clay (47%). The pore architecture and acidic sites of the zeolites seems to influence the product selectivity.
Graphical abstractMonoallyl guaiacol such as eugenol, o-eugenol and chavibetol were synthesized by the allylation of guaiacol using zeolite HY. Among zeolites, HY gave maximum guaiacol conversion (46%) with 85% selectivity for monoallyl guaiacol under optimum reaction conditions. Figure optionsDownload full-size imageDownload as PowerPoint slide