Article ID Journal Published Year Pages File Type
69123 Journal of Molecular Catalysis A: Chemical 2006 5 Pages PDF
Abstract

Monoallyl guaiacol such as eugenol, o-eugenol and chavibetol are industrially important compounds, which were synthesized by the allylation of guaiacol using zeolite HY. The reaction was performed in an autoclave in the temperature range 140–200 °C and allyl alcohol to guaiacol mole ratio 1:4, under nitrogen pressure. Among zeolites, HY gave maximum guaiacol conversion (46%) compared to H-beta (28%), H-mordenite (15%) and HZSM-5 (4%) when compared under identical reaction conditions. Zeolites showed better selectivity (>85%) for monoallyl guaiacol than K-10 montmorillonite clay (47%). The pore architecture and acidic sites of the zeolites seems to influence the product selectivity.

Graphical abstractMonoallyl guaiacol such as eugenol, o-eugenol and chavibetol were synthesized by the allylation of guaiacol using zeolite HY. Among zeolites, HY gave maximum guaiacol conversion (46%) with 85% selectivity for monoallyl guaiacol under optimum reaction conditions. Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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