Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
69169 | Journal of Molecular Catalysis A: Chemical | 2006 | 9 Pages |
Abstract
New trimeric quaternary ammonium salts derived from cinchonine or cinchonidine bridging N,N′-bis(ethyl)-4-(methyl)-phenyl-amine moiety are used as a chiral phase transfer catalysts for the asymmetric alkylation of a N-(diphenylmethylene)glycine tert-butyl ester with very good chemical yield (up to 97%) and ee's (up to 98%).
Graphical abstractNew trimeric Cinchona alkaloid-based quaternary ammonium salts as efficient chiral phase transfer catalysts for enantioselective synthesis of α-amino acids. Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Ayyanar Siva, Eagambaram Murugan,