Article ID Journal Published Year Pages File Type
693081 Progress in Organic Coatings 2013 6 Pages PDF
Abstract

A superhydrophobic surface was created on poly(vinylchloride)-coated architectural fabric using spray coating method. Dispersions of nanoparticles and a flourochemical were prepared as top coating solutions. After spray-dry-cure process, contact angle, sliding (tilt) angle, 3 M water repellency test and surface morphology were compared between uncoated and top coated PVC surfaces. The results indicated that a specific nano-TiO2 dispersion top coating produced a superhydrophobic layer on the top of the PVC surface with high contact angle (150°) and very low sliding angle (2°). Combination of two major requirements, the magnified of the degree of roughness and low surface energy, created self-cleaning effect on the PVC surface. Abrasion fastness of superhydrophobic top coating was improved by surface oxidation via UV–ozone surface treatments. Spectroscopic analysis demonstrated that formation of oxygenated functional groups has improved PVC wettability and adhesion. Results of artificial weathering test indicated no change in superhydrophobicity of top coated PVC.

► Fabrication of ultrahydrophobic architectural fabric was achieved by spray coating. ► Surface roughness and energy was manipulated by nanoparticles and flourochemical. ► Specific nano TiO2 top coating produced PVC surface with very low sliding angle (2°). ► Surface oxidation via UV–ozone treatment improved abrasion fastness. ► Artificial weathering indicated no change in superhydrophobicity of top coated PVC.

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Physical Sciences and Engineering Chemical Engineering Process Chemistry and Technology
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