Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6969949 | Journal of Hazardous Materials | 2016 | 9 Pages |
Abstract
We investigated the concentration levels, fractionation and molecular weight distribution (MWD) of dissolved organic matter (DOM) and metals (V, Cr, Co, Ni, Cu, Zn, As, Cd, Sn, Ba, Hg and Pb) in a polluted groundwater from an industrial area in Northern Sweden. DOM was mainly recovered in the hydrophobic acidic and hydrophobic neutral sub-fractions (45 and 35%, respectively) while most metals were found in the acidic sub-fractions (46-93%) except for V, Fe and As, which were predominant in the basic sub-fractions (74-93%) and Cd in the neutral ones (50%). DOM exhibited a broad MWD in groundwaters, usually from 5 to 200Â kDa and was dominated by high molecular weight hydrophobic acids, low molecular weight hydrophilic acids and hydrophilic neutral compounds. Most of the studied metals (Fe, Cr, Co, Sn, Ba, Hg) were associated with the high molecular weight DOM fraction (ca. 40-100Â kDa). Cu, Pb, Zn, Cd and Ni interacted with a broad range of DOM size fractions but were still most abundant in the high molecular weight fraction. Few metal/metalloids (As, V and Cr in some cases) presented a very weak affinity for DOM and presumably existed predominantly as “free” inorganic ions in solution.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Ivan Kozyatnyk, Sylvain Bouchet, Erik Björn, Peter Haglund,