Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7043846 | Separation and Purification Technology | 2018 | 9 Pages |
Abstract
In this work, self-synthesized halloysite nanotube-hydrous ferric dioxide (HNT-HFO) nanocomposites prepared via chemical precipitation method were incorporated in polyethersulfone (PES) to fabricate novel ultrafiltration (UF) mixed matrix membranes (MMMs) for oil-water separation process. Prior to filtration experiments, the morphologies and physicochemical properties of prepared HNT-HFO nanocomposites and MMMs were characterized using scanning electron microscope with energy-dispersive X-ray, transmission electron microscope, Fourier-transform Infrared spectroscope, atomic force microscope and contact angle goniometer. It was found that the membrane contact angle decreased remarkably from 81.39° to about 50.30° upon addition of 23.08â¯wt% of HNT-HFO nanocomposite (2.0 loading ratio) in the PES matrix. The improved surface hydrophilicity resulted in the flux enhancement in the MMM, achieving close to 650â¯L/m2â¯hâ¯bar of pure water flux. This value was about 10 times higher than the flux shown by the pristine PES membrane. In addition to the excellent water flux, the MMM also exhibited almost complete elimination of oil molecules (99.7% rejection) when tested with 1000â¯ppm oily solution. The findings indicated the potential use of the newly developed MMMs for efficient purification of oily wastewater in the oil field and refinery processes.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Syarifah Nazirah Wan Ikhsan, Norhaniza Yusof, Farhana Aziz, Nurasyikin Misdan, Ahmad Fauzi Ismail, Woei-Jye Lau, Juhana Jaafar, Wan Norharyati Wan Salleh, Nur Hanis Hayati Hairom,