Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7043924 | Separation and Purification Technology | 2018 | 21 Pages |
Abstract
We present benchmark adsorption data of CH4, CO2 and N2 binary and ternary mixtures on MOF-5 at 297â¯K and pressures up to 1500â¯kPa obtained via the isotope exchange technique (IET) and a predictive volumetric method. The ternary mixtures data are organized in two different domains: constant composition and constant pressure planes. The constant composition data show quasi-constant selectivity in the entire pressure range. The constant pressure data showed the existence of azeotrope-like crossover for CH4 along the N2 and CO2 paths. However, these crossovers do not correspond to a reversal in the adsorbent's affinity for CH4. The obtained experimental data is in accord with ideal adsorption solution theory (IAST).
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
F.A Kloutse, A. Hourri, S. Natarajan, P. Benard, R. Chahine,