Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7062115 | Thermochimica Acta | 2017 | 7 Pages |
Abstract
Mechanisms and kinetics of non-isothermal polymerization of N,Nâ²-bismaleimide-4,4â²-diphenylmethane (BMI) with 1,3-dimethylbarbituric acid (13BTA) were investigated. Competition between free radical polymerization and Michael addition reaction mechanisms for the BMI/13BTA reaction system was characterized by using DSC and 1H NMR technique. Model-free (isoconversional) method was used to determine triplet kinetic parameters for the polymerization of BMI with 13BTA. Average activation energy (Eα) and pre-exponential factor (Aα) are ca. 56 kJ molâ1 and 65.83 Ã 105 minâ1 in the fractional conversion (α) range 0.1-0.9, respectively. Particle nucleation involved in the polymerization process was satisfactorily predicted by the nucleation Avrami-Erofeev model {f(α) = n(1 â α)[âln(1 â α)](nâ1)/n} with n = 1.46. The z-average particle size of microgel particles was measured by dynamic light scattering, which supported the particle nucleation and growth process.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
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Authors
Quoc-Thai Pham, Jung-Mu Hsu, Wan-Ju Shao, Yu-Xuan Zhan, Fu-Ming Wang, Chorng-Shyan Chern,