Article ID Journal Published Year Pages File Type
7062553 Thermochimica Acta 2012 5 Pages PDF
Abstract
▸ A new coulometric titration setup is presented. ▸ The major source of error in the presented coulometric titration setup is the oxygen leakage through the YSZ solid electrolytes. ▸ The oxygen leakage through the YSZ solid electrolyte is modeled by the permeation of oxygen according to the ambipolar conductivity model. ▸ Reducing the difference in chemical potential of oxygen between the inside and the outside of the cell decreases the electrochemical leakage of oxygen into the cell.
Related Topics
Physical Sciences and Engineering Chemical Engineering Fluid Flow and Transfer Processes
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