Article ID Journal Published Year Pages File Type
7066136 Bioresource Technology 2018 35 Pages PDF
Abstract
The present study systematically investigated the combustion characteristics of spent mushroom substrate (SMS) using TG-MS (thermogravimetric/mass spectrometry) and TG-FTIR (thermogravimetric/Fourier transform infrared spectrometry) under five heating rates. The physicochemical characteristics and combustion index pointed to SMS as a promising biofuel for power generation. The high correlation coefficient of the fitting plots and similar activation energy calculated by various methods indicated that four suitable iso-conversional methods were used. The activation energy varied from 130.06 to 192.95 kJ/mol with a mean value of 171.49 kJ/mol using Flynn-Wall-Ozawa and decreased with the increased conversion degree. The most common emissions peaked at the range of 200-400 °C corresponding to volatile combustion stage, except for CO2, NO2 and NO. The peak CO2 emission occurred at 439.11 °C mainly due to the combustion of fixed carbon.
Related Topics
Physical Sciences and Engineering Chemical Engineering Process Chemistry and Technology
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