Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7082039 | Bioresource Technology | 2013 | 10 Pages |
Abstract
Pyrolysis of real wastes (MPW and MSW) has been investigated at 500 °C, 550 °C and 600 °C using Y-zeolite, β-zeolite, equilibrium FCC, MoO3, Ni-Mo-catalyst, HZSM-5 and Al(OH)3 as catalysts. The viscosity of pyrolysis oils could be decreased by the using of catalysts, especially by β-zeolite and MoO3. Both carbon frame and double bound isomerization was found in case of thermo-catalytic pyrolysis. Char morphology and texture analysis showed more coke deposits on the catalyst surface using MSW raw material. Pyrolysis oils had K, S, P Cl, Ca, Zn, Fe, Cr, Br and Sb as contaminants; and the concentrations of K, S, P, Cl and Br could be decreased by the using of catalysts.
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Authors
Norbert Miskolczi, Funda AteÅ, Nikolett Borsodi,