| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7084998 | Bioresource Technology | 2012 | 8 Pages |
Abstract
⺠The mechanism for phenolics oxidation by bacterial laccases is proposed for the first time. ⺠The efficiency of laccase-mediator system using phenolics is independent of the enzymes properties. ⺠Reactivity vs. stability of phenoxy radicals is a key issue in the laccase-mediator systems. ⺠C-O coupling products were identified from a newly putative radical coupling route. ⺠A catalytic cycle of laccase-mediator systems with an interplay of competitive routes is proposed.
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Authors
Tânia Rosado, Pedro Bernardo, Kamila Koci, Ana V. Coelho, M. Paula Robalo, LÃgia O. Martins,