| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7087795 | Bioresource Technology | 2012 | 8 Pages |
Abstract
⺠The thermal behavior of virgin and reprocessed PLA under pyrolysis is assessed by TGA. ⺠A novel function (TDB) and a new parameter (ZDT) to model thermal stability are given. ⺠The technologies for the control of gases can be transferred to treat reprocessed PLA. ⺠Six kinetic methods are effectively combined into a complete kinetic methodology. ⺠The trigger of thermal decomposition increases up to the third recyclate of PLA.
Keywords
MPTFlynn–Wall–OzawaEvolved gas analysis (EGA)2D-IRThermal decomposition behaviorPolylactide (PLA)TDBMPGEGAMPFDTGAβPMCMPETGAAICActivation energyFourier-transform infrared spectroscopyThermogravimetric analysisEvolved gas analysisDegree of conversionAdvanced isoconversional methodThermal decomposition kineticsFT-IRtwo-dimensional infrared spectroscopyPre-exponential factorMALDI-TOF-MSReprocessingPyrolysisKAS
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Process Chemistry and Technology
Authors
J.D. Badia, L. Santonja-Blasco, A. MartÃnez-Felipe, A. Ribes-Greus,