Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7214018 | Composites Science and Technology | 2018 | 8 Pages |
Abstract
Segregated highly conductive percolation networks in nanocomposites consisting of a polymethyl methacrylate (PMMA) core and multi-walled carbon nanotube (MWCNT)-shell were investigated experimentally as a means of exploring the relationship between the micro-dimensional size of spherical polymer particles and the number of coated MWCNT layers by a new theoretical approach of filler monolayer model. The measured electrical conductivity of the core-shell structured complex utilizing 20â¯Î¼m PMMA spheres showed that percolation was achieved at a very low filler content of 0.0099â¯wt% MWCNTs, whereas 0.149â¯wt% MWCNT was required to achieve percolation when 5â¯Î¼m PMMA spheres were utilized. The size of PMMA cores was attributed to the percolation threshold, and conductivity was enhanced by increased layers of MWCNT coating. The percolation behaviors based on the theoretical model and experimental data were elucidated. Furthermore, an advanced theoretical model for prediction of number of MWCNT monolayers was provided.
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Authors
Seung Han Ryu, Hong-Baek Cho, Seil Kim, Young-Tae Kwon, Jimin Lee, Kee-Ryung Park, Yong-Ho Choa,