Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7233622 | Biosensors and Bioelectronics | 2014 | 4 Pages |
Abstract
This paper describes an investigation of a facile colorimetric sensor for Hg2+ in aqueous solution based on the anti-aggregation of silver nanoparticles (AgNPs). In the absence of Hg2+, the addition of 6-Thioguanine to AgNPs solution led to the aggregation of AgNPs, resulting in a color change from yellow to brown with a red shift of absorption spectra. However, the presence of Hg2+ inhibited the 6-Thioguanine-induced aggregation of AgNPs accompanying with a color change from brown to yellow. Under the optimal conditions, the ratio between the absorbance at 530Â nm and 394Â nm (A530/A394) was linearly proportional to the Hg2+ concentration in a range from 0 to 333Â nM with a detection limit of 4Â nM. Other environmentally relevant metal ions did not interfere with the detection of Hg2+. The proposed method was simple, cost-effective and rapid without any complicated modifying step. It was successfully applied to detect Hg2+ in environmental water samples.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Junling Duan, Hongzong Yin, Ranran Wei, Weiwei Wang,