Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7483093 | Journal of Environmental Management | 2015 | 11 Pages |
Abstract
It is difficult to eliminate phosphate from large volumes of water in batch mode using an adsorbent such as andosol. In a fixed-bed column, andosol has a very low permeability. In this study, andosol was mixed with bagasse to increase permeability. The mixture was then applied for the adsorption of phosphate in a fixed-bed column. Optimum and stable permeability was obtained with a 50/50 mixture of andosol and bagasse. The maximum adsorption capacity obtained was 4.18Â mg/g for a column with a bed depth of 1.8Â cm and a flow rate of 4Â mL/min. The experimental data fit best to Thomas and Adam-Bohart models. These experimental results were applied in the treatment of natural phosphate-containing water from Yaoundé Municipal Lake in Cameroon. Column performance increased by 60% due to the presence of Ca2+ and Mg2+ in the natural water. These cations form complexes with phosphate at the andosol surface. The standard enthalpy 15.964Â kj/mol indicated that phosphate adsorption on andosol-bagasse mixture was an endothermic process. Kinetic experiments demonstrated that phosphate adsorption fitted better with a pseudo-second-order model.
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Authors
Emmanuel Djoufac Woumfo, Jean Mermoz Siéwé, Daniel Njopwouo,