| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7603818 | International Journal of Mass Spectrometry | 2016 | 8 Pages |
Abstract
- New laser-desorption mass spectrometer for spectroscopy of size-selected cluster ions.
- Optical photodissociation spectra of Au4+ and Au4+·H2O clusters are analyzed.
- Structures are derived from global optimization and long-range corrected DFT calculations.
- H2O adds to the most stable Au4+ rhomboid (D2h) with an AuO bond of 1.15Â eV.
- The partially covalent AuO bond in Au4+·H2O is much weaker than in Au+·H2O.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Bertram Klaus August Jaeger, Marco Savoca, Otto Dopfer, Nguyen Xuan Truong,