Article ID Journal Published Year Pages File Type
7603871 International Journal of Mass Spectrometry 2016 6 Pages PDF
Abstract

- The absolute total and partial cross sections of electron ionization on triethylborane are measured.
- The major ionization product ions in the electron energy range of 6.6-200 eV are the parent ion BC6H15+ and fragment ions BC4H10+ and BC2H6+.
- Gas-phase ion-molecule reactions of triethylborane with selected hydrocarbon ions and boron-containing ions are studied.
- The mechanisms forming two common product ions from the ion-molecule reactions, BC4H10+ and BC2H6+, are via simple ethide transfer and via ethide transfer followed by dissociation (loss of C2H4), respectively.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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