Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7604030 | International Journal of Mass Spectrometry | 2015 | 8 Pages |
Abstract
- The CS bond in the methane sulfinate ligand cleaves to yield CH3 and SO2.
- CID yields complexes with lanthanides coordinated by sulfur dioxide anion.
- CID products reveal stabilities of lanthanide divalent oxidation states.
- Lanthanides preferentially bond to oxygen whereas copper bonds to carbon.
- DFT predicts observed fragmentation chemistry.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Yu Gong, Maria C. Michelini, John K. Gibson,