| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7604253 | International Journal of Mass Spectrometry | 2015 | 7 Pages |
Abstract
- Fragmentation kinetics of KYGGFL and RYGGFL examined using resonant ejection SID.
- RRKM modeling provides dissociation parameters for individual reaction channels.
- Basic residue has a pronounced effect on the kinetics of the b2 ion formation Similar kinetics of the b5+H2O ion formation observed for KYGGFL and RYGGFL .
- Strikingly different kinetics of the b2 ion formation is attributed to different mechanisms
- A salt-bridge pathway (RYGGFL) and canonical pathway (KYGGFL) of the b2 ion formation.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Julia Laskin,