Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7604366 | International Journal of Mass Spectrometry | 2015 | 8 Pages |
Abstract
- Gas-phase reactivity of phenoxyl radical cations of aromatic nitrogen bases is studied.
- Reactivity towards NO and C3H7SH decreases as N+-Hâ¯O distance decreases.
- Reactivity decreases as spin density at the oxygen atom decreases.
- LysTyr(O) radical cation is stabilized by hydrogen bonding at the radical site.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Michael Lesslie, Andrii Piatkivskyi, John Lawler, Travis R. Helgren, Sandra Osburn, Richard A.J. O'Hair, Victor Ryzhov,