| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7604495 | International Journal of Mass Spectrometry | 2015 | 7 Pages |
Abstract
- APPI in-source fragmentation mechanism of Substance P was investigated.
- Toluene exhibits a low adiabatic ionization energy due to vibrational excitation.
- Substance P ions originate from pneumatic nebulization then from charge reduction.
- c-Type fragments originate from ECD-like process on the doubly charged species.
- b/y-Type fragments originate from decomposition of neutrals followed by proton transfer.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Marie Méjean, Alexandre Giuliani, Alain Brunelle, David Touboul,