Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7605189 | International Journal of Mass Spectrometry | 2014 | 7 Pages |
Abstract
- Ca2+ interactions with DMSO in water environment using ESI-MS and DFT calculations.
- The number of DMSO ligands in [Ca(DMSO)x]2+ depends on the temperature.
- With increasing capillary temperature the number of DMSO ligands decreases.
- With increasing capillary temperature water molecules substitute the DMSO ligands.
- The bonding energy of DMSO to Ca2+ is strongly influenced by the presence of water.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Michal Jakl, Michal Straka, Jana Jaklová Dytrtová, Jana Roithová,