Article ID Journal Published Year Pages File Type
7605189 International Journal of Mass Spectrometry 2014 7 Pages PDF
Abstract

- Ca2+ interactions with DMSO in water environment using ESI-MS and DFT calculations.
- The number of DMSO ligands in [Ca(DMSO)x]2+ depends on the temperature.
- With increasing capillary temperature the number of DMSO ligands decreases.
- With increasing capillary temperature water molecules substitute the DMSO ligands.
- The bonding energy of DMSO to Ca2+ is strongly influenced by the presence of water.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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