Article ID Journal Published Year Pages File Type
7605280 International Journal of Mass Spectrometry 2013 7 Pages PDF
Abstract

- Azo-containing compound used as a CID-labile reagent for chemical cross-linking (XL).
- CID of peptide-azo-peptide ions yields N2 loss and open shell peptide product ions.
- ESI-MSn of interpeptide and intrapeptide XL demonstrates proof-of-principle.
- The distonic nature of peptide radical cations is proved by ion-molecule reactions.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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