Article ID Journal Published Year Pages File Type
7605297 International Journal of Mass Spectrometry 2013 8 Pages PDF
Abstract

- Fluoride and chloride complexes with 1,3,5-trinitrobenzene (TNB) are obtained.
- TNB-F− conforms to a strongly covalent σ-complex structure.
- TNB-Cl− displays an off-center binding of chlorine, described as weakly covalent.
- Also TNB-I− and TNB-Br− present IR features consistent with a weak σ-binding motif.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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