Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7605336 | International Journal of Mass Spectrometry | 2013 | 6 Pages |
Abstract
Theory and experiment agree that the encounter complex [NH2C(O2)OHOCH2]
- + is the key starting configuration for the three product ions observed. These are: NH2C(OOH)OH+, the hydrogen-bridged ion [CH2OHN(H)CO]+ and NH2C(O2)OH
- +, generated by loss of HCO
- , O2H
- and CH2O respectively. The peroxide-type ion NH2C(O2)OH
- + generated in this experiment is not observed in the reaction of solitary ions NH2COH
- + with O2, which is ascribed to the stabilizing effect of the CH2O dipole in the terbody encounter complex.
- + is the key starting configuration for the three product ions observed. These are: NH2C(OOH)OH+, the hydrogen-bridged ion [CH2OHN(H)CO]+ and NH2C(O2)OH
- +, generated by loss of HCO
- , O2H
- and CH2O respectively. The peroxide-type ion NH2C(O2)OH
- + generated in this experiment is not observed in the reaction of solitary ions NH2COH
- + with O2, which is ascribed to the stabilizing effect of the CH2O dipole in the terbody encounter complex.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Karl J. Jobst, Johan K. Terlouw, Julien De Winter, Pascal Gerbaux,