| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7605370 | International Journal of Mass Spectrometry | 2013 | 8 Pages |
Abstract
- Complexes of CuH+ and ZnH+ with H2NCH2CH2NH2 eliminate Cu(0) and Zn(0).
- Experiment and theory agree that the associated TS is larger for the zinc complex.
- The high TS for the zinc complex allows competition with NH3 loss.
- N-methyl substitution has no effect on the behaviour of the CuH+ complex ions.
- In contrast, N-methyl substituted complexes with ZnH+ predominantly loses ZnH2.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Karl J. Jobst, Johan K. Terlouw, Paul J.A. Ruttink, Peter C. Burgers,