| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7605595 | International Journal of Mass Spectrometry | 2013 | 8 Pages |
Abstract
- We investigated the biomolecular cluster ions formed in a supersonic jet by resonance enhanced multi photon ionization.
- Fragmentation of the biomolecular cluster ions leads to the formation of protonated peptide ions.
- It is shown that the ionization of the cluster is described by a dissociative proton transfer to the N-terminal end of the peptide by isotopic labeling.
- Fragmentation of the protonated peptides is conducted through a proton chain walk.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Osama Abdelrahman, Barbara Grotemeyer, Jürgen Grotemeyer,