Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7605809 | International Journal of Mass Spectrometry | 2012 | 7 Pages |
Abstract
⺠Intracluster ion-molecule reactions of vanadium ion and alkyl acetate were studied. ⺠Competitive V+ insertions and fragmentation mechanism were proposed. ⺠Evidence for H atom migration within heteroclusters is provided by isotope-labeling experiments. ⺠Density functional theory calculations rationalize the reaction pathways and energetics.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Dababrata Paul, Kiryong Hong, Tae Kyu Kim, Jun-Sik Oh, Kwang-Woo Jung,