Article ID Journal Published Year Pages File Type
7605809 International Journal of Mass Spectrometry 2012 7 Pages PDF
Abstract
► Intracluster ion-molecule reactions of vanadium ion and alkyl acetate were studied. ► Competitive V+ insertions and fragmentation mechanism were proposed. ► Evidence for H atom migration within heteroclusters is provided by isotope-labeling experiments. ► Density functional theory calculations rationalize the reaction pathways and energetics.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
Authors
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