Article ID Journal Published Year Pages File Type
7606358 Journal of Analytical and Applied Pyrolysis 2018 13 Pages PDF
Abstract
A set of fixed-bed biomass pyrolysis reactor incorporated with three-stage condensation columns was constructed in this study, and the effects of pyrolysis temperature, carrier gas flow rate and condensation temperature on biomass pyrolysis products were discussed systematically. Results show that as the pyrolysis temperature increased, the yield of liquid products initially increased with a maximum yield at 550 °C and then decreased. When the temperatures of the three-stage condensers were 110 °C, 0 °C, and −196 °C, the highest yields of bio-oil in each condenser were accordingly obtained at 550 °C, 450 °C, and 500 °C, respectively. Carrier gas flow rate and fractional condensation temperature indicated minimal influence on the total yield of liquid products. However, fractional condensation temperature had an obvious effect on the yields of the fractions. Gas chromatography/mass spectrometry revealed that the first fraction contained abundant phenolic compounds, the second fraction contained medium-boiling compounds with relatively high concentrations of water, acids, and ketones and the last fraction contained a minimal amount of hydrocarbons and water. Furthermore, higher pyrolysis temperature resulted in a higher yield of phenol products, whereas higher condensation temperature led to a higher concentration of phenols and dehydrated carbohydrates.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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