Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7606516 | Journal of Analytical and Applied Pyrolysis | 2018 | 6 Pages |
Abstract
Current studies describe the application of simultaneous TG-DTA-FTIR techniques in the in-situ synthesis of potassium carbonate (K2CO3) from the thermal decomposition of potassium tetraoxalate dihydrate [KH3(C2O4)2.2H2O]. Progress of the decomposition reactions with increasing temperatures was monitored online through TG mass loss, corresponding heat effects and evolved gases. Sequential formation of anhydrous potassium tetraoxalate, potassium hydrogen oxalate [KHC2O4] and potassium oxalate [K2C2O4] was confirmed using thermal, ATR â FTIR and PXRD measurements. The intermediate potassium oxalate undergoes structural transformation and then decomposes to potassium carbonate by the temperature of 600â¯Â°C. PXRD measurements confirm the formation of K2CO3 and the results are in agreement with ATR â FTIR and thermal analysis.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Naina Raje, Bhupesh B. Kalekar, Darshana K. Ghonge,