Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7640446 | Microchemical Journal | 2018 | 24 Pages |
Abstract
We contributed to the speciation analysis of PA complexes with Ln and An, for which published studies are very scarce. Th-PA species with stoichiometries 1:1, [ThPA]3+ to 1:6, [ThPA6]2â were observed. The 1:1 species showed its prevalence under most conditions studied. PA showed to form complexes with Nd with stoichiometries 1:1, [NdPA]2+ to 1:4, [NdPA4]â. The 1:3 species seems to gain dominance as PA concentration increase. Speciation analysis of Th and Nd with mixtures of ligands and in a spiked real sample is also presented.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Mariela Soledad Espinosa, Roberto Servant, Paola Alejandra Babay,