Article ID Journal Published Year Pages File Type
7672440 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2014 5 Pages PDF
Abstract

- The radial integrals 〈rk〉4f, k = 2, 4, 6, of Nd3+ ion are derived semi-empirically.
- The dielectric screening model used relates spectroscopic and dielectric properties.
- The range of the 〈rk〉4f values is close to those from relativistic computations.
- The mean nephelauxetic ratio is related to covalency and bonding parameters.
- This approach is sensitive to the particular crystal containing Nd3+ ions.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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