Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7681914 | Talanta | 2013 | 8 Pages |
Abstract
In the present study, multiwalled carbon nanotubes (MWCNT)/graphene oxide (GO) nanocomposite was prepared by homogenous dispersion of MWCNT and GO and used for the simultaneous voltammetric determination of dopamine (DA) and paracetamol (PA). The TEM results confirmed that MWCNT walls were wrapped well with GO sheets. The MWCNT/GO nanocomposite showed superior electrocatalytic activity towards the oxidation of DA and PA, when compared with either pristine MWCNT or GO. The major reason for the efficient simultaneous detection of DA and PA at nanocomposite was the synergistic effect between MWCNT and GO. The electrochemical oxidation of DA and PA was investigated by cyclic voltammetry, differential pulse voltammetry and amperometry. The nanocomposite modified electrode showed electrocatalytic oxidation of DA and PA in the linear response range from 0.2 to 400 µmol Lâ1 and 0.5 to 400 µmol Lâ1 with the detection limit of 22 nmol Lâ1 and 47 nmol Lâ1 respectively. The proposed sensor displayed good selectivity, sensitivity, stability with appreciable consistency and precision.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Srikanth Cheemalapati, Selvakumar Palanisamy, Veerappan Mani, Shen-Ming Chen,