Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7691971 | Arabian Journal of Chemistry | 2017 | 12 Pages |
Abstract
Disperse dyeing of nylon and wool fibers with two new nanosized copper(II) complexes including phosphoric triamide ligands with formula Cu(NO3)2L2 (1) and Cu(CH3COO)2L2 (2) where LÂ =Â 4-NO2C6H4NHP(O)(NC4H8O)2 (A) was performed successfully. Both complexes 1 and 2 produced yellow and green colored nylon and wool fabrics, respectively. The complexes were synthesized by ultrasonic method and characterized by 1H, 13C, 31P NMR, Fourier-transform infrared, photoluminescence, ultraviolet-visible spectroscopy, X-ray diffraction, field-emission microscopy and elemental analysis. The FE-SEM micrographs revealed that the nanoparticles of these compounds are spherical in morphology and â¼17-20Â nm in size. Very appropriate washfastness while poor lightfastness results were deduced for the dyed fibers. The in vitro antibacterial activities of the dyes 1, 2 and dyed wool/nylon fibers against the Gram-positive Bacillus subtilis bacterium illustrated increasing in the antibacterial effect by increasing the dye concentration from 0.1% to 0.5% o.w.f. on both wool and nylon dyed fibers.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Zahra Shariatinia, Shahla Shekarriz, Hourieh Sadat Mirhosseini Mousavi, Narges Maghsoudi, Zahra Nikfar,