Article ID Journal Published Year Pages File Type
7694664 Current Opinion in Chemical Biology 2015 13 Pages PDF
Abstract

- Water oxidation and dioxygen reduction are important in fuel cell technology.
- Role of metal-oxo cores as vital intermediates in these reactions is reviewed.
- Subtle electronic changes can drastically affect the metal-oxo reactivity.
- Metal-hydroperoxo acts as a metal-oxo precursor during dioxygen reduction.
- Possible role of calcium in dioxygen release during water oxidation is discussed.
Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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