Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7701985 | Ultrasonics Sonochemistry | 2018 | 36 Pages |
Abstract
Two new hydrated monocationic Cu(II) complexes with 1,3-propylenediamine and 1,2-ethylenediamine of general formula [CuBr(N-N)2·H2O]Br were prepared. The complexes were identified by means of several spectroscopic tools (Uv-visible, IR and MS), thermally (TG/DTA) and CHN-elemental analysis. The three dimensional structure for complex A and B was provide by X-ray diffraction studies and showed the Cu(II) ion as 4â¯+â¯1â¯+â¯1 coordinated, four nitrogen atoms of the diamine ligands, one bromide ion and one H2O semi-coordinated to the Cu(II) center, a typical trans effect is clearly observed in the two complexes. The molecular crystal structures are linked via several H-bonds like N_Hâ¦Br and N_Hâ¦O. Additionally, intra-molecular H-bonds of kind C_Hâ¦Br is observed; these interactions lead to crystal structure three dimensional architecture packing. Hirshfeld surfaces (HSA) analysis was served to figure out the inter-contacts and fingerprints atoms percentage. DNA-binding, antitumor and antibacterial effectiveness of the desired complexes were evaluated.
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Physical Sciences and Engineering
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Authors
Ismail Warad, Firas F. Awwadi, Bahaa Abd Al-Ghani, Ashraf Sawafta, Naveen Shivalingegowda, Neartur Krishnappagowda Lokanath, Mohammad S. Mubarak, Taibi Ben Hadda, Abdelkader Zarrouk, Fuad Al-Rimawi, Abdallah Bani Odeh, Sameer A. Barghouthi,