Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7744175 | Solid State Ionics | 2018 | 6 Pages |
Abstract
Uniform and thin ZrF4 nanolayer with diverse contents are successfully coated on the surface of spinel-structured LiNi0.5Mn1.5O4 (LNMO) material with Fd3¯m space group via a simple co-precipitation process. The morphologies and structures of the as-prepared samples are studied by X-ray diffraction (XRD), Raman, scanning electron microscopy (SEM), energy dispersive spectrometric (EDS) analyses and high resolution transmission electron microscopy (HRTEM). Electrochemical measurements demonstrate that a desirable capacity retention of 95.5% could be obtained for 2â¯wt% ZrF4-surface modified LNMO after 120â¯cycles, much greater than that of 80.1% for the pure material. Meanwhile, 2â¯wt% ZrF4 modified sample shows superior rate performance, which delivers a high capacity of 106â¯mAhâ¯gâ1 at 2C. Intensive electrochemical impedance spectroscopy (EIS) and Fourier transform infrared (FTIR) analyses indicate that ZrF4 surface modification is effective in stabilizing the electrode/electrolyte interface at high voltage, through averting the direct contact and depressing the undesirable side reactions between cathode and electrolyte. The ZrF4 surface modification on LNMO proposed herein, with a facile and repeatable strategy, provides a perspective in enhancing surface structural stability as well as electrochemical reversibility for electrode functionalization.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Yaping Li, Dandan Wang, Tinghua Xu, Muying Wu, Du Pan, Huiling Zhao, Ying Bai,