Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7745422 | Solid State Ionics | 2016 | 4 Pages |
Abstract
A novel molecular crystal, Li{N(SO2CF3)2}(C6H4(OCH3)2) (1), was synthesized by heating LiTFSA with DMB in 1:1 molar ratio. Single crystal x-ray diffraction study of 1 revealed that the compound possesses a dinuclear structure with five-coordinate lithium centers bridged by TFSA anions. AC impedance measurements showed that ionic conduction through the crystallites of 1 takes place via a hopping mechanism at ambient temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Makoto Moriya, Daiki Kato, Yoshiko Hayakawa, Wataru Sakamoto, Toshinobu Yogo,