Article ID Journal Published Year Pages File Type
7745822 Solid State Ionics 2014 7 Pages PDF
Abstract
We propose to represent or document all the isothermal and nonisothermal mass/charge transport properties of mixed ionic electronic conductor compounds in terms of a simple Onsager transport coefficient matrix. To this end, the general equations of motion for mobile ions and electrons are formulated, complying with the irreversible thermodynamic rules, in terms of experimentally operable forces, and the measurement principles of the Onsager matrix are introduced on the basis of the chemical polarization in isothermal semi-blocking and nonisothermal complete-blocking conditions.
Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
Authors
, , ,