| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7747312 | Solid State Ionics | 2012 | 5 Pages |
Abstract
The XPS and NEXAFS data indicate a decomposition of the CoN4 (chelate-) complex during pyrolysis. The N1s data for 800 °C show graphite-like, formally pyrrolic and pyridinic like features, without any significant contribution of Co. The Co2p data for both, XPS and NEXAFS are dominated by CoO/Co2O3. It can be concluded that during the pyrolysis cobalt particles are formed by the disintegration of CoN4-centers, after pyrolysis these particles become oxidized upon contact with air.
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Authors
K. Müller, M. Richter, D. Friedrich, I. Paloumpa, U.I. Kramm, D. SchmeiÃer,