Article ID Journal Published Year Pages File Type
7747383 Solid State Ionics 2012 5 Pages PDF
Abstract
► The submitted paper points out the temperature dependency of the Ni-agglomeration in SOFCs. Therefore, Ni/CGO anode microstructures reduced at different temperatures were quantitatively analyzed using a sophisticated approach for the continuous particle size distribution. ► Most of the microstructural changes occur above a reduction temperature of 850 °C which can therefore be considered as a critical temperature for SOFCs. ► The Ni-agglomeration as a function of the reduction temperature was described with an Arrhenius type equation, by which the experimental results could be fitted very well. ► The study will be one important part of a degradation model on Ni-cermet anodes that is currently under development. ► To our knowledge this is the first study on Ni-cermet SOFCs that proposes an Arrhenius equation based on real experimental results.
Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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