Article ID Journal Published Year Pages File Type
7747426 Coordination Chemistry Reviews 2018 29 Pages PDF
Abstract
In the last two decades, tremendous progress has been made towards the development of compounds with s- and p-block elements. β-Diketiminate ligands have been widely used in coordination chemistry due to their versatile tunability in both electronic and steric properties. Aluminum complexes stabilized by β-diketiminate ligands have been widely explored in stoichiometric studies to activate small molecules. This review article highlights the recent progress of aluminum complexes supported by β-diketiminate ligands and Cp∗(pentamethylcyclopentadienyl) substituents with univalent aluminum as reagents as well as aluminum hydrides in reactions.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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