Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7747522 | Coordination Chemistry Reviews | 2018 | 26 Pages |
Abstract
This review covers compounds formed by Mannich-like reactions of coordinated amine-compounds with an α-methylene nitro-compound (usually nitroethane) and an aldehyde (predominantly formaldehyde) to form a compound with two primary amine functions joined by a -NH-(CH2)-C(NO2)(CH3)-(CH2)-NH- link, forming a new chelate ring. Most reported compounds have tetraaza-macrocyclic ligands. Copper(II) is the usual “templating” metal ion, with compounds of nickel(II), palladium(II), platinum(II) and gold(III) also reported. The refcodes of compound with structures in the Cambridge Crystallographic Data Centre files are listed and structural figures of representative examples shown.99
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Neil F. Curtis,