Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7748003 | Coordination Chemistry Reviews | 2015 | 49 Pages |
Abstract
3d-4f heterometallic discrete complexes have enjoyed increasing attraction in recent decades because of their potential advantages to create new single-molecule magnets: the moderate magnetic couplings between 3d and 4f spin carriers and significant single-ion magnetic anisotropies of 4f ions. Herein we review the synthetic strategy, structures and magnetic properties of 3d-4f discrete complexes. Particular attention is paid in this review to the examples showing dynamics of the magnetization.
Keywords
HeterometallicSingle-chain magnetPIVXMCDHSABSMMMCESCMMetallacrownHMP2-Hydroxymethylpyridine2,6-pyridinedicarboxylic acidDFTo-VanillinSingle-molecule magnetSingle-ion magnetSingle-molecule magnetsMagnetocaloric effectSynthetic strategySalicylic acidSalicylhydroxamic acidPivalic acidhard and soft acids and basesX-ray magnetic circular dichroismBenzoatetriethanolamineStructural diversityQuantum tunneling of magnetizationDi-2-pyridyl ketoneDibenzoylmethaneSIMPhenanthrolinePhenmethyldiethanolamineMagnetismPRODensity functional theoryHexafluoroacetylacetoneHydrotris(pyrazolyl)borateProlineGlyGlycine
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ke Liu, Wei Shi, Peng Cheng,