Radical ligand-containing single-molecule magnets

Article ID	Journal	Published Year	Pages	File Type
7748011	Coordination Chemistry Reviews	2015	35 Pages	PDF

Abstract

- We review the current literature of radical ligand-containing single-molecule magnets.
- We also briefly overview other classes of metal-ligand radical complexes that could be used to design new single-molecule magnets.
- Ligand-field and electronic structure considerations in dictating exchange strength and slow magnetic relaxation are emphasized.

Keywords

NAP Cp′ISQ CBVd Tppz Pentamethylcyclopentadienyl AZP TCNE Tetrathiafulvalene TCNQ HFAC IPR tBu HMM CTh CPP tert-butyl TBA PDI PIC τ0 TFA DAD TTF 2,2′:6′,2″-Terpyridine 2,2′-Bipyridine Cp*Tetrabutylammonium Tetracyanoquinodimethane Tetracyanoethylene Salen Single-molecule magnets ethyl ind Indazole Iso-propyl Imidazole Benzyl butyl Terpy Tris(2-aminoethyl)amine Tris(2-pyridylmethyl)amine Zero-field splitting Exchange coupling bipy Di-2-pyridylamine TEMPO Coercive field Phthalocyanine phenyl TREN Radical ligands Redox-active ligands Methyl Naphthalene Hydrotris(pyrazolyl)borate PROXYL Pyridine Picolinate