Towards multifunctional magnetic systems through molecular-programmed self assembly of Re(IV) metalloligands

Article ID	Journal	Published Year	Pages	File Type
7748021	Coordination Chemistry Reviews	2015	84 Pages	PDF

Abstract

- The huge spin-orbit coupling costant of the ReIV ion generates high values of D.
- ReIV complexes can exhibit magnetic ordering through spin canting or SIM behaviour.
- Strengthening of the magnetic coupling when compared with analogous 3d systems.
- Some ReIV species with didentate N-heterocyclic ligands can induce apoptosis.

Keywords

SCMs DEF PDZ DMB DBF MECN Cyclam Lα DPPE bpy Field-cooled magnetization FCM Single-ion magnets Rhenium(IV) complexes 2-Pyrazinecarboxylic acid SMMs PPh3 HPZ H2ox Hacac dmbpy DMF INS PND DMA DCM cps DEA DMP THF 1-Vinylimidazole 1,10-Phenanthroline 1,2-Bis(diphenylphosphino)ethane 1,4,8,11-tetraazacyclotetradecane 2-Propanol 2,2′:6′,2″-Terpyridine 2,2′-Bipyridine 2,2′-bipyrimidine 2,2′-Biimidazole 2,9-Dimethyl-1,10-phenanthroline 4,4′-bpy 4,4′-Dimethyl-2,2′-bipyridine 4,4′-Bipyridine DFT N,N-Dimethylacetamide N,N-dimethylformamide Single-chain magnets Single-molecule magnets Acetonitrile Acetylacetone Oxalic acid Malonic acid Triphenylphosphine oxide Imidazole HIM Tetrahydrofuran Terpy Triphenylphosphine pyz diethylformamide Dichloromethane SIMS Schiff-base Metallosupramolecular chemistry Phen Heterometallic complexes Density functional theory Nitromethane Polarized neutron diffraction Inelastic neutron scattering Pyrazole Coordination polymers Pyrazine Pyridazine Pyridine Pyrimidine pym tetraphenylphosphonium cation