Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7748131 | Coordination Chemistry Reviews | 2014 | 20 Pages |
Abstract
- teaH3 and RdeaH2 are popular ligands towards SMMs and magnetocaloric compounds.
- We review the synthesis routes to 3dâ4f and 4f compounds with these ligands.
- We review the bonding of these ligands with metals in these compounds.
- We review the magnetic properties of these compounds as SMMs and refrigerants.
- We assess the suitability of these ligands to these applications.
Keywords
CASSCFJ12ZFSIsopropoxideCASPT2SMMBVSMCEd.c.isobutyrateTHFIproA.C.nuclear magnetic resonance1,4,7-TriazacyclononaneTaCNSingle-molecule magnetMagnetocaloric effectAcetylacetonePivalic acidBenzoic acidBenzotriazoleBoltzmann constantTetrahydrofurantriethanolamineNMRMagnetic entropy changeAdiabatic temperature changeZero-field splittingQuantum tunnellingCoupling constantAlternating currentDirect CurrentSusceptibilityTaudiethanolamineCoordination chemistryPhthalocyanineLanthanidemethyldiethanolamineBond valence sumMagnetismApplied magnetic fieldMicrostatePyridineJahn–Teller
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Joseph W. Sharples, David Collison,