| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7751015 | Inorganica Chimica Acta | 2016 | 6 Pages |
Abstract
The HSiCl3 was treated with 2-[N-(2,6-diisopropylphenyl)iminomethyl]indolyl lithium (DippIMIndLi) or 2-[N-(2,6-diisopropylphenyl)iminomethyl]phenyl lithium (DippIMPhLi) to give either disubstituted (DippAMInd)(DippIMInd)SiCl (2) or stable CHN â Si coordinated silane (DippIMPh)SiHCl2 (3). Heating of 3 provided the hydrosilylated compound (DippAMPh)SiCl2 (4). Therefore, it has been demonstrated that the rate of CHN imino group reduction strongly depends on the type of the anionic ligand.53
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hana HoÅ¡nová, Miroslav Novák, Libor Dostál, Zdenka RůžiÄková, Roman Jambor,